Indians are fascinated with gold, making India one of the largest consumers of the yellow metal globally. Now Indian scientists have tinkered with the chemistry of the material and turned it into ‘black gold’ which they say can be potentially used for applications ranging from solar energy harvesting to desalinating seawater.
Scientists at the Mumbai-based Tata Institute of Fundamental Research (TIFR) used gold nanoparticles and by rearranging size and gaps between them developed a new material which has unique properties such as capacity to absorb light and carbon dioxide. Gold does not have these properties, therefore ‘black gold’ is being called a new material. In appearance it is black, hence the name ‘black gold.’
The findings have been announced in Chemical Science, a scientific journal published by the Royal Society of Chemistry.
“We have not doped gold nanoparticles with any other material or added other materials. We varied inter-particle distance between gold nanoparticles using a cycle-by-cycle growth approach by optimizing the nucleation-growth step, using dendritic fibrous nanosilica, whose fibers were used as the deposition site for gold nanoparticles,” explained Vivek Polshettiwar, who led the research team, while speaking to India Science Wire.
Prof. Vivek Polshettiwar with research team at TIFR, Mumbai
"We varied inter-particle distance between gold nanoparticles using a cycle-by-cycle growth approach by optimizing the nucleation-growth step, using dendritic fibrous nanosilica, whose fibers were used as the deposition site for gold nanoparticles "
One of the most fascinating properties of the new material is its ability to absorb the entire visible and near-infrared region of solar light. It does so because of inter-particle plasmonic coupling as well as heterogeneity in nanoparticle size. Black gold could also act as a catalyst and could convert carbon dioxide into methane at atmospheric pressure and temperature using solar energy.
“If we develop an artificial tree with leaves made out of back gold, it can perform artificial photosynthesis, capturing carbon dioxide and converting it into fuel and other useful chemicals,” added Prof Polshettiwar. The efficiency of conversion of carbon dioxide into fuel, at present, is low but researchers believe it could be improved in future.
In order to study solar energy harvesting ability of the new material, researchers dispersed it into water and exposed the solution to light for one hour and the temperature of the solution was measured. The temperature of the solution with pure silica spheres rose to 38 degrees while the ones with different concentrations of black gold rose to 67 to 88 degrees. The maximum increase in temperature was attributed creation of thermal hotspots due to the heterogeneity of the particle sizes as well as optimum inter- particle coupling.
Researchers said the material can be used as a nano-heater to covert seawater into potable water with good efficiency. “Our results indicate the potential application of black gold in purification of seawater to potable water via steam generation using solar energy under atmospheric reaction conditions,” according to the researchers.
Kabeer Jasuja (Indian Institute of Technology – Gandhinagar), who is not connected with the study, commented that "It is amazing to see these elegantly designed assemblies of gold nanoparticles could function as artificial leaves and capture the solar energy. This study is a significant step in current efforts towards reducing carbon footprint. It would be promising to see how the synthesis of these colloidosomes can be scaled up in the future."
The research team included Mahak Dhiman, Ayan Maity, Anirban Das, Rajesh Belgamwar, Bhagyashree Chalke and Vivek Polshettiwar (TIFT); Yeonhee Lee, Kyunjong Sim and Jwa-Min Nam (Seoul National University). The study was funded by the Department of Science and Technology (DST) and the Department of Atomic Energy (DAE).
India Science Wire